2 Xi-Chang Zhang, Fei-Fei Wu, Shijun Li, Ji-Ning Zhou, Jing Wu, Ning Li, Wenjun Fang, Kim Hung Lam, Albert S. C. Chan. Unraveling Organocuprate Complexity: Fundamental Insights into Intrinsic Group Transfer Selectivity in Alkylation Reactions. Lewis Base-Catalyzed Enantioselective Conjugate Reduction of β,β-Disubstituted α,β-Unsaturated Ketones with Trichlorosilane: E/Z-Isomerization, Regioselectivity, and Synthetic Applications. 2 1,4-Addition of aryl boronic acids to α,β-unsaturated ketones catalyzed by a CCC–NHC pincer rhodium complex. Top Gear reviews the Mini Hatch. 6 Copper( Copper-Catalyzed Propargylic Reduction with Diisobutylaluminum Hydride. Mechanisms of Nucleophilic Organocopper(I) Reactions. Meryem Benohoud, Sakari Tuokko, Petri M. Pihko. Sandro Cacchi, Giancarlo Fabrizi, Antonia Iazzetti, Carmela Molinaro, Rosanna Verdiglione, Antonella Goggiamani. Stereoselective Synthesis of α-Branched Amines by Nucleophilic Addition of Unstabilized Carbanions to Imines. Enantioselective Copper-Catalyzed Alkylation of Quinoline Copper(I)-catalyzed stereoselective hydrogenation of 1,3-diynes and enynes. Chiral ferrocenyl phosphine-phosphoramidite ligands for Cu-catalyzed asymmetric conjugate reduction of α,β-unsaturated esters. 31,279 Fans. 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A reaction pathway involving a ketene intermediate is proposed. A dinuclear silver hydride and an umpolung reaction of CO2. N 6 Copper-catalyzed highly efficient ester formation from carboxylic acids/esters and formates. Cluster transformation of [Cu Copper(II) Hydride CuH2 Molar Mass, Molecular Weight. Hui Peng, Jinhui Ma, Lingfei Duan, Guangwen Zhang. Yang Yang, Ian B. Perry, and Stephen L. Buchwald . Study of High-Power Ultrasound-Assisted Processes Using Copper-Containing Precursors in Aqueous Media. Karin Garcés, Francisco J. Fernández-Alvarez, Pilar García-Orduña, Fernando J. Lahoz, Jesús J. Pérez-Torrente, Luis A. Oro. Palladium(II)-Catalyzed Cross-Dehydrogenative Coupling (CDC) of N-Phthaloyl Dehydroalanine Esters with Simple Arenes: Stereoselective Synthesis of Z-Dehydrophenylalanine Derivatives. Ling Liu, Xiaonian Li, Hong Dong, Chuan Wu. Asymmetric Synthesis of Remote Quaternary Centers by Copper-Catalyzed Desymmetrization: An Enantioselective Total Synthesis of (+)-Mesembrine. Enantioselective Synthesis of 3‐Substituted Cyclobutenes by Catalytic Conjugate Addition/Trapping Strategies. Yuya Miki, Koji Hirano, Tetsuya Satoh, and Masahiro Miura . New MINI Countryman S E plug-in hybrid 2017 review ... MINI says 90 per cent of its buyers drive only 30-40 miles per day, making a compelling argument for this latest Cooper S E ALL4. Xichang Dong, Andreas Weickgenannt, Martin Oestreich. Eleni Vasilikogiannaki, Ioannis Titilas, Charis Gryparis, Anastasia Louka, Ioannis N. Lykakis, Manolis Stratakis. Linus P. Bheeter, Mickaël Henrion, Michael J. Chetcuti, Christophe Darcel, Vincent Ritleng, Jean-Baptiste Sortais. Jun Liu, Changdong Shao, Yanghui Zhang, Guangfa Shi, Shulei Pan. . 3 Upon treatment with a standard base, copper hydride converts to metal oxocuprate(1−) and hydrogen gas. A unique copper-catalyzed cross-coupling reaction by hydrogen (H Stereoselective Synthesis of Unsymmetrical β,β-Diarylacrylates by a Heck−Matsuda Reaction: Versatile Building Blocks for Asymmetric Synthesis of β,β-Diphenylpropanoates, 3-Aryl-indole, and 4-Aryl-3,4-dihydro-quinolin-2-one and Formal Synthesis of (−)-Indatraline. Reduction of copper hydride gives copper metal. Copper-Catalyzed Enantioselective Hydrogenation of Ketones. 2 Are Alkyne Reductions Chemo-, Regio-, and Stereoselective Enough To Provide Pure (Z)-Olefins in Polyfunctionalized Bioactive Molecules?. Enantioselective Total Syntheses of (−)-Rhazinilam, (−)-Leucomidine B, and (+)-Leuconodine F. Chemoselective catalytic reduction of conjugated α,β-unsaturated ketones to saturated ketones via a hydroboration/protodeboronation strategy. André P. Dieskau, Jeanne-Marie Begouin, Bernd Plietker. 3 β′ Diselenophosphate-Induced Conversion of an Achiral [Cu Directed Cobalt-Catalyzed anti-Markovnikov Hydroalkylation of Unactivated Alkenes Enabled by “Co–H” Catalysis. Regioselective reductions of β,β-disubstituted enones catalyzed by nonracemically ligated copper hydride. Mechanistic insights into the catalytic carbonyl hydrosilylation by cationic [CpM(CO) Copper(I)-Catalyzed Dehydrative C-Glycosidation of Unprotected Pyranoses with Ketones. (IMes)] Enantioselective Synthesis of Trisubstituted Allenyl–B(pin) Compounds by Phosphine–Cu-Catalyzed 1,3-Enyne Hydroboration. ) removal for the stereoselective synthesis of 3-phosphoindoles. E. Vrancken, J.-M. Campagne, P. Mangeney. Sonochemical synthesis of copper hydride (CuH). Migratory Reductive Acylation between Alkyl Halides or Alkenes and Alkyl Carboxylic Acids by Nickel Catalysis. Christopher R. Waidmann, L. A. Daiane Cristina Sass, Vladimir Constantino Gomes Heleno, Simone Cavalcante, Jader da Silva Barbosa, Ana Carolina Ferreira Soares, and Mauricio Gomes Constantino . Grace B. Panetti, Jerome R. Robinson, Patrick J. Carroll, Michael R. Gau, Brain C. Manor, Patrick J. Walsh, Eric J. Schelter. Takayuki Nakajima, Yoshia Kamiryo, Kanae Hachiken, Kanako Nakamae, Yasuyuki Ura. 3 From £14,620 8. ](BF Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes. Similar to other metal hydrides, copper (I) hydride is pyrophoric, but unlike them, it is not water reactive. The Sealy Copper II Plush mattress is a medium-soft feeling mattress and we rated it 6 on our 10 point Comfort Scale (a 1 is hard, 10 is softest). Since the first report on the synthesis of copper hydride complex [Cu6H6(PPh3)6] in 1971, copper hydride reagents have been utilized in a variety of organic transformation. Kinetische Racematspaltung α‐hydroxysubstituierter Oximether durch enantioselektive Cu‐H‐katalysierte Si‐O‐Kupplung. 2 Niklas O. Thiel, Sebastian Kemper, Johannes F. Teichert. Thomas Vergote, Sonia Gharbi, François Billard, Olivier Riant, Tom Leyssens. Synthesis of 7-Epineoptilocaulin, Mirabilin B, and Isoptilocaulin. Cupric Hydride. 1,2-Addition of Dihydrogen across Rhodium(III)–OMe Bonds. Boosting Molecular Complexity with O Jingwei Li, Wuming Yan, and Yoshito Kishi . Enantioselective Synthesis of (R)-Tolterodine via CuH-Catalyzed Asymmetric Conjugate Reduction. Copper(ii)-catalyzed enantioselective hydrosilylation of halo-substituted alkyl aryl and heteroaryl ketones: asymmetric synthesis of (R)-fluoxetine and (S)-duloxetine. )]. Remote sp3 C–H Amination of Alkenes with Nitroarenes. Synthesis of (−)-Hebelophyllene E: An Entry to Geminal Dimethyl-Cyclobutanes by [2+2] Cycloaddition of Alkenes and Allenoates. β Transition-metal catalyzed enantioselective hydrofunctionalization of alkynes. Heterometallic Hydride Complexes of Rare-Earth Metals and Ruthenium through C–H Bond Activation. Unified Synthesis of C1–C19 Building Blocks of Halichondrins via Selective Activation/Coupling of Polyhalogenated Nucleophiles in (Ni)/Cr-Mediated Reactions. Kong Ching Wong, Elvis Ng, Wing-Tak Wong, Pauline Chiu. 2 Promotion of Henry reactions using Cu(OTf)2 and a sterically hindered Schiff base: access to enantioenriched β-hydroxynitroalkanes. Enantioselective Copper-Catalyzed Reductive Coupling of Alkenylazaarenes with Ketones. Follow The Cooper Review. Cu( Thomas Vergote, Fady Nahra, Alain Merschaert, Olivier Riant, Daniel Peeters, and Tom Leyssens . Non-coordinating-Anion-Directed Reversal of Activation Site: Selective C−H Bond Activation of A brief review of state-of-the art is reported on metal hydrides. Nickel-Catalyzed Hydrofluorination of Unactivated Alkenes through a HAT Pathway. Ken Motokura, Naoki Takahashi, Akimitsu Miyaji, Yasuharu Sakamoto, Sho Yamaguchi, Toshihide Baba. Zining Wang, Xiaxia He, Rui Zhang, Ge Zhang, Guoxing Xu, Qian Zhang, Tao Xiong, and Qian Zhang . Michael W. Gribble, Jr., Michael T. Pirnot, Jeffrey S. Bandar, Richard Y. Liu, and Stephen L. Buchwald . Byung Chul Kang, Sung Ho Shin, Jaesook Yun, and Do Hyun Ryu . The use of Cu–NHC complexes in catalysis is reviewed. Fragment Coupling Reactions in Total Synthesis That Form Carbon–Carbon Bonds via Carbanionic or Free Radical Intermediates. New Design of Periphery-Functionalized Ligands and Their Application in Transition-Metal-Catalyzed Reactions. Formation of Nitriles, Carboxylic Acids, and Derivatives by Oxidation, Substitution, and Addition. 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